Briggs-Rauscher reaction with Cobra SMARTsense reaction Principle The Briggs-Rauscher reaction is a so-called homogeneous oscillating reaction, i.e. the reaction rate of the complete process is subject to periodic fluctuations. In general, oscillating reactions can always occur when the following conditions are fulfilled: The reaction must run highly exergonic (ΔG << 0). At least one of the reaction steps must contain a positive or negative back-coupling. Such back-coupling processes occur when the result of the individual partial steps of the reaction, such as changes in temperature or concentration, act back on the rate constants of the individual partial steps of the reaction. In this way, the whole reaction becomes non-linear. Benefits - Simplified implementation: all pre-settings already prepared
- Spectacular experiment with numerous color changes
Tasks Observer the fluctuations of the Briggs-Rauscher reaction by measuring the potential over a definite time period. Learning objectives - Oscillating reactions
- Exergonic process
- Potential
- Briggs-Rauscher reaction
Necessary accessories - Precision balance 620g/0.001g
This experiment requires a computer. Software provided. Scope of delivery
Cobra SMARTsense ORP - Sensor for measuring the redox potential ±2000 mV (Bluetooth)
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12927-00
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1
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measureLAB, multi-user license
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14580-61
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1
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Holder for Cobra SMARTsense
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12960-00
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1
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USB charger for Cobra SMARTsense and Cobra4
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07938-99
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1
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Adapter, BNC male/4 mm female pair
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07542-26
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1
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Teclu burner, DIN, natural gas
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32171-05
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1
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Safety gas tubing, DVGW, sold by metre
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39281-10
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1
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Hose clip f.12-20 diameter tube
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40995-00
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2
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Lighter f.natural/liquified gases
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38874-00
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1
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Tripod, ring-d=100 mm, h=180 mm
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33299-00
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1
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Wire gauze 120x120mm, ceramic cen.
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33287-03
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1
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Reference electrode, AgCl
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18475-00
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1
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Platinum electrode in protection tube, d = 8 mm
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45206-00
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1
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Connecting cable, 32 A, red, various lengths
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07361-01
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1
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Retort stand, h = 750 mm
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37694-00
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1
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Right angle boss-head clamp
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37697-00
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2
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Holder for two electrodes
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45284-01
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1
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Spring balance holder
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03065-20
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2
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Beakers, Boro, low form, various sizes
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46055-00
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1
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Beakers, Boro, low form, various sizes
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46060-00
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2
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Beakers, Boro, high form, various sizes
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46025-00
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2
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Beakers, Boro, high form, various sizes
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46029-00
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1
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Glass rod, boro 3.3, l=200mm, d=5mm
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40485-03
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1
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Graduated cylinders, Boro, various sizes
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36629-00
|
1
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Magnetic stirrer without heating, 3 ltr., 230 V
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35761-99
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1
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Magnetic stirring bar 30 mm, cylindrical
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46299-02
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1
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Powder spatula, steel, 180 mm
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47561-00
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1
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Wash bottle, plastic, 500 ml
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33931-00
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1
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Protecting glasses, clear glass
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39316-00
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1
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Gloves, Neoprene, size M
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46347-00
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1
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Boiling beads, 200 g
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36937-20
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1
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Pasteur pipettes, 3ml, PE, 500pcs
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36616-00
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1
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Potassium iodate 100 g
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31443-10
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1
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Sulphuric acid, 95-97%, 500 ml
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30219-50
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1
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Malonic acid 100 g
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31551-10
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1
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Manganese-II sulphate 250 g
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31559-25
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1
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Starch,soluble 100 g
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30227-10
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1
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Hydrogen peroxide, 30%, 250 ml
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31710-25
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1
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Water, distilled 5 l
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31246-81
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1
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