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Technical data


Briggs-Rauscher reaction with Cobra SMARTsense reaction

Article no: P3121667

Principle

The Briggs-Rauscher reaction is a so-called homogeneous oscillating reaction, i.e. the reaction rate of the complete process is subject to periodic fluctuations. In general, oscillating reactions can always occur when the following conditions are fulfilled: The reaction must run highly exergonic (ΔG << 0). At least one of the reaction steps must contain a positive or negative back-coupling. Such back-coupling processes occur when the result of the individual partial steps of the reaction, such as changes in temperature or concentration, act back on the rate constants of the individual partial steps of the reaction. In this way, the whole reaction becomes non-linear.

Benefits

  • Simplified implementation: all pre-settings already prepared
  • Spectacular experiment with numerous color changes

Tasks

Observer the fluctuations of the Briggs-Rauscher reaction by measuring the potential over a definite time period.

Learning objectives

  • Oscillating reactions
  • Exergonic process
  • Potential
  • Briggs-Rauscher reaction

Necessary accessories

  • Precision balance 620g/0.001g

This experiment requires a computer. Software provided.

Scope of delivery

Cobra SMARTsense ORP - Sensor for measuring the redox potential ±2000 mV (Bluetooth) 12927-00 1
measureLAB, multi-user license 14580-61 1
Holder for Cobra SMARTsense 12960-00 1
USB charger for Cobra SMARTsense and Cobra4 07938-99 1
Adapter, BNC male/4 mm female pair 07542-26 1
Teclu burner, DIN, natural gas 32171-05 1
Safety gas tubing, DVGW, sold by metre 39281-10 1
Hose clip f.12-20 diameter tube 40995-00 2
Lighter f.natural/liquified gases 38874-00 1
Tripod, ring-d=100 mm, h=180 mm 33299-00 1
Wire gauze 120x120mm, ceramic cen. 33287-03 1
Reference electrode, AgCl 18475-00 1
Platinum electrode in protection tube, d = 8 mm 45206-00 1
Connecting cable, 32 A, red, various lengths 07361-01 1
Retort stand, h = 750 mm 37694-00 1
Right angle boss-head clamp 37697-00 2
Holder for two electrodes 45284-01 1
Spring balance holder 03065-20 2
Beakers, Boro, low form, various sizes 46055-00 1
Beakers, Boro, low form, various sizes 46060-00 2
Beakers, Boro, high form, various sizes 46025-00 2
Beakers, Boro, high form, various sizes 46029-00 1
Glass rod, boro 3.3, l=200mm, d=5mm 40485-03 1
Graduated cylinders, Boro, various sizes 36629-00 1
Magnetic stirrer without heating, 3 ltr., 230 V 35761-99 1
Magnetic stirring bar 30 mm, cylindrical 46299-02 1
Powder spatula, steel, 180 mm 47561-00 1
Wash bottle, plastic, 500 ml 33931-00 1
Protecting glasses, clear glass 39316-00 1
Gloves, Neoprene, size M 46347-00 1
Boiling beads, 200 g 36937-20 1
Pasteur pipettes, 3ml, PE, 500pcs 36616-00 1
Potassium iodate 100 g 31443-10 1
Sulphuric acid, 95-97%, 500 ml 30219-50 1
Malonic acid 100 g 31551-10 1
Manganese-II sulphate 250 g 31559-25 1
Starch,soluble 100 g 30227-10 1
Hydrogen peroxide, 30%, 250 ml 31710-25 1
Water, distilled 5 l 31246-81 1

PHYWE Systeme GmbH & Co. KG
Robert-Bosch-Breite 10 – 37079 Göttingen – Germany
www.phywe.com