Freezing point depression Principle The freezing point of a solution is lower than that of the pure solvent. The depression of the freezing point can be determined experimentally using a suitable apparatus (cryoscopy). If the cryoscopy constants of the solvent are known, the molecular mass of the substance dissolved can be determined. Benefits - All relevant measured variables at a glance
- Experimentation made easy by intuitive operation
- With detailed experiment guide
Tasks - Determine the size of freezing point depression after dissolving a strong electrolyte (NaCl) in water.
- Determine the number of ions into which the electrolyte dissociates.
- Determine the molar mass of a non-electrolyte (hydroquinone) from the value of freezing point depression.
Learning objectives - Raoult's law
- Cryoscopic constant
- Chemical potential
- Gibbs-Helmholtz equation
- Concentration ratio
- Degree of dissociation
- Van't Hoff factor
Necessary accessories - Precision balance 620g/0.001g
Scope of delivery
Magnetic stirring bar 30 mm, cylindrical
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46299-02
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1
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Supp.rod stainl.st.,50cm,M10-thr.
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02022-20
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1
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Right angle boss-head clamp
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37697-00
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2
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Universal clamp
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37715-01
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2
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Apparatus for freezing point depression
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36821-00
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1
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Gasket for GL25, 12mm hole, 10pcs
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41243-03
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1
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Temperature meter digital, 4-2
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13618-00
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1
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Sheath Thermocouple, NiCr-Ni, Type K, -40°C ... +1000°C
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13615-06
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2
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Protective sleeves f.temp.probe,2
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11762-05
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1
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Beakers, Boro, low form, various sizes
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46057-00
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1
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Bulb pipettes, various sizes
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36581-00
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1
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Pipettor
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36592-00
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1
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Wash bottle, plastic, 500 ml
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33931-00
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1
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Digital stopwatch, 24 h, 1/100 s and 1 s
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24025-00
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1
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Pellet press for calorimeter
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04403-04
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1
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Mortar w. pestle, 70ml, porcelain
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32603-00
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2
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Microspoon, steel
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33393-00
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1
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Spoon, special steel
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33398-00
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1
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Funnel, diameter = 50 mm, plastic (PP)
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36890-00
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1
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Weighing dishes, square shape, 84 x 84 x 24 mm, 500 pcs.
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45019-50
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1
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Pasteur pipettes, 250 pcs
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36590-00
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1
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Rubber caps, 10 pcs
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39275-03
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1
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Glass stirring rod, d = 8 mm, l = approx. 300 mm
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40485-06
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1
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Sodium chloride, 500 g
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30155-50
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1
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Hydroquinone 250 g
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30089-25
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1
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Denaturated alcohol (spirit for burning), 1000 ml
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31150-70
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1
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Water, distilled 5 l
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31246-81
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1
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Universal power supply, 600mA 3/4.5/5/6/7.5/9/12V, incl. 9 adaptors
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11078-99
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1
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